107264-00-6 Usage
Description
1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE is a white crystalline powder that serves as a versatile reagent in various chemical reactions due to its unique chemical properties.
Uses
Used in Chemical Synthesis:
1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE is used as a reactant for Pd(II)-catalyzed para-selective C-H arylation, enabling the selective formation of desired products in the presence of a palladium catalyst.
Used in Fluorination Reactions:
1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE is utilized as a reactant in fluorination reactions, where it aids in the introduction of a fluorine atom into a molecule, which is crucial for various pharmaceutical and chemical applications.
Used in Oxidative Processes:
1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE acts as an oxidant in oxidatively-induced aryl-CF3 bond-formation, promoting the formation of aryl-trifluoromethyl (aryl-CF3) bonds, which are important in the synthesis of various organic compounds.
Used in Pd(II)-catalyzed C-H Olefination Reactions:
The compound is employed as a reactant in Pd(II)-catalyzed C-H olefination reactions, where it facilitates the formation of olefins from alkanes through the C-H activation process, which is a significant step in the synthesis of complex organic molecules.
Check Digit Verification of cas no
The CAS Registry Mumber 107264-00-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,7,2,6 and 4 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 107264-00:
(8*1)+(7*0)+(6*7)+(5*2)+(4*6)+(3*4)+(2*0)+(1*0)=96
96 % 10 = 6
So 107264-00-6 is a valid CAS Registry Number.
InChI:InChI=1/C8H11FN.CHF3O3S/c1-6-4-7(2)10(9)8(3)5-6;2-1(3,4)8(5,6)7/h4-5H,1-3H3;(H,5,6,7)/q+1;/p-1
107264-00-6Relevant articles and documents
Efficient hydrolysis of dithioacetals by the N-fluoro-2,4,6-trimethylpyridinium triflate-water system
Kiselyov,Strekowski,Semenov
, p. 2151 - 2158 (2007/10/02)
Dithioacetals including 1,3-dithianes and 1,3-dithiolanes are efficiently cleaved by the title reagent system to the parent carbonyl compounds. The cleavage of diprotected symmetrical α-diketones and p-phenylenediketones gives monoketones in good yields. Amide, 1,3-dioxolane, disulfide, ester, ether, hydroxy, nitrile, nitro, and sulfide functions are relatively stable under the cleavage conditions but thiols are oxidized to disulfides.
N-FLUOROPYRIDINIUM TRIFLATE AND ITS ANALOGS, THE FIRST STABLE 1:1 SALTS OF PYRIDINE NUCLEUS AND HALOGEN ATOM
Umemoto, Teruo,Tomita, Kyoichi
, p. 3271 - 3274 (2007/10/02)
N-Fluoropyridinium salts having non-nucleophilic counter-anions and their derivatives were synthesized by treating pyridine-F2 adducts with strong Broensted acids, their salts or trimethylsilyl esters, of Lewis acids, or by allowing F2 to react with N-trimethylsilylpyridinium salts.
