107272-42-4

Basic information

• Product Name: FRh(C₂F₄)(P(C₆H₅)3)2
• CAS NO: 107272-42-4
• Molecular Weight: 746.501
• Mol File: 107272-42-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: FRh(C₂F₄)(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: FRh(C₂F₄)(P(C₆H₅)3)2(107272-42-4)
• EPA Substance Registry System: FRh(C₂F₄)(P(C₆H₅)3)2(107272-42-4)

Safety Data

• Hazardous Substances Data: 107272-42-4(Hazardous Substances Data)

Upstream product

• 12216-72-7 ClRh(C₂F₄)(P(C₆H₅)3)2 
• 150746-76-2 tris(dimethylamino)sulfonium trimethylsilyldifluoride 

Downstream Products

• 58167-05-8 fluorocarbonylbis(triphenylphosphine)rhodium(I) 
• 107272-43-5 CF₃SO₃Rh(C₂F₄)(P(C₆H₅)3)2 

Relevant articles and documents

Fluoroorganometallic chemistry: Synthesis, structure, and chemistry of the cubane cluster [FRh(C2H4)(C2F4)]4

The fluoro-bridged cluster [FRh(C2H4)(C2F4)]4 was prepared by treatment of [ClRh(C2H4)(C2F4)]2 with AgBF4, followed by reaction with [(CH3)2N]3S+(CH3) 3SiF2-. The cubanelike structure of the tetrameric complex was established by X-ray crystallography. Reaction of [FRh(C2H4)(C2F4)]4 with P(C6H5)3 yielded the new monometallic complex FRh(C2F4)[P(C6H5)3] 2. The monometallic rhodium-fluoride complex can undergo reactions involving ligand substitution or fluoride extraction. In a ligand substitution reaction, solutions of FRh(C2F4)[P(C6H5)3] 2 react with CO to give FRh(CO) [P(C6H5)3]2. Reaction with (CH3)3SiO3SCF3 yielded CF3SO3Rh(C2F4)[P(C6H 5)3]2, derived from the fluoride extraction reaction.