107282-80-4

Basic information

• Product Name: C₄₂H₅₆B₁₂ClNP₂Ru
• CAS NO: 107282-80-4
• Molecular Weight: 903.116
• Mol File: 107282-80-4.mol

Chemical Properties

• CAS DataBase Reference: C₄₂H₅₆B₁₂ClNP₂Ru(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₂H₅₆B₁₂ClNP₂Ru(107282-80-4)
• EPA Substance Registry System: C₄₂H₅₆B₁₂ClNP₂Ru(107282-80-4)

Safety Data

• Hazardous Substances Data: 107282-80-4(Hazardous Substances Data)

Upstream product

• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 

Relevant articles and documents

Ruthenium(II) Complexes of closo-Dodecaboranyl Anions and the Molecular Structure of the pileo Thirteen-vertex Ruthenaborane

Reaction of Na2 with gives a 10percent yield of the lemon-yellow air-stable covalent complex , characterized by elemental analysis and multielement nuclear magnetic single- and multiple-resonance spectroscopy.Reaction of 2 and results in the formation of as an orange-red air-stable compound (30percent), characterized by single-crystal X-ray diffraction analysis as well as n.m.r. spectroscopy.The solvate .CH2Cl2 forms monoclinic crystals, with a = 2 246.3(2), b = 1 189.2(2), c = 1 972.5(2) pm, β = 111.04(1) deg, Z = 4, an space group P21/n.The compounds may formally be regarded either as ruthenium(II) complexes of closo-dodecaboranyl ligands which bind in a trihapto tridentate mode to the octahedral metal centres via three two-electron three-centre B-H-Ru bridge bonds, or as 13-vertex pileo 2n-electron metallaborane cluster species which have capped closed deltahedral cluster geometries.