1072844-44-0Relevant articles and documents
Total synthesis of (±)-trichodermamide B and of a putative biosynthetic precursor to aspergillazine A using an oxaza-cope rearrangement
Lu, Chong-Dao,Zakarian, Armen
, p. 6829 - 6831 (2008)
(Chemical Equation Presented) Coping with tandem reactions: The total synthesis of marine fungal metabolite, trichodermamide B, is accomplished using a tandem nitrosation/oxaza-Cope rearrangement as the key step to establish the characteristic heterocyclic ring system of the natural product. Preparation of the putative biosynthetic precursor of aspergillazine A provides further insight into the possible biosynthetic pathway to aspergillazines.
