1072935-03-5Relevant articles and documents
Synthesis, characterization, and theoretical studies of metal complexes derived from the chiral tripyridyldiamine ligand Bn-CDPy3
Abouelatta, Ahmed I.,Sonk, Jason A.,Hammoud, Mirvat M.,Zurcher, Danielle M.,McKamie, Joshua J.,Schlegel, H. Bernhard,Kodanko, Jeremy J.
, p. 5202 - 5211 (2010)
Synthesis and characterization of metal complexes of the chiral tripyridyldiamine ligand Bn-CDPy3 (1), derived from trans-1,2- diaminocyclohexane, are described, along with theoretical studies that support the experimental data. These studies confirm that
Influence of the backbone of N5-pentadentate ligands on the catalytic performance of Ni(II) complexes for electrochemical water oxidation in neutral aqueous solutions
Shen, Junyu,Wang, Mei,He, Tianhao,Jiang, Jian,Hu, Maowei
, p. 9019 - 9022 (2018)
Two N5-chelated nickel complexes displayed decent catalytic activity and good stability for electrochemical water oxidation in phosphate buffer solutions at pH 7, with observed rate constants of 3.06 and 4.62 s-1, which are higher than those reported so far for molecular nickel catalysts in neutral solutions. The results revealed that the rigid backbone of N5-chelating ligands has a positive influence on the activity of the nickel catalysts.