107301-62-2Relevant articles and documents
Iodocarbamation of N-Homopropargyl Carbamates: Mild and Stereoselective Entry to Functionalized Oxazinan-2-ones
Quinodoz, Pierre,Quelhas, Alexandre,Wright, Karen,Drouillat, Bruno,Marrot, Jér?me,Couty, Fran?ois
supporting information, p. 2621 - 2626 (2017/05/19)
An efficient and general iodocarbamation of benzyl N-homopropargylcarbamates has been developed by using iodine as the electrophilic agent. This regio- and stereoselective cyclization yielded (E)-6-iodomethyleneoxazinan-2-ones, which can be further transformed through palladium cross-coupling reactions followed by hydrogenation to produce 1,3-oxazinan-2-ones.