1073190-31-4Relevant articles and documents
Amphoteric Homotropic Allosteric Association between a Hexakis-Urea Receptor and Dihydrogen Phosphate
Kondo, Seiya,Masuda, Junya,Komiyama, Tomoki,Yasuda, Nobuhiro,Takaya, Hikaru,Yamanaka, Masamichi
, p. 16201 - 16206 (2019)
Conformationally flexible hexakis-urea 1 was synthesized efficiently by condensing hexakis(aminomethyl)benzene with 4-nitrophenyl-(3,5-di-tert-butylphenyl)carbamate. The hexakis-urea 1 is unexpectedly soluble in organic solvents of low polarity due to int
Molecules with new topologies derived from hydrogen-bonded dimers of tetraurea calix[4]arenes
Bogdan, Anca,Bolte, Michael,Boehmer, Volker
supporting information; experimental part, p. 8514 - 8520 (2009/09/29)
Tetraurea calix[4]arenes 2 have been synthesized in which two adjacent aryl urea residues are connected to a loop by an aliphatic chain -O-(CH 2)n-O-. The remaining urea residues have a bulky 3,5-di-tert-butylphenyl residue and an ω-alkenyloxyphenyl residue. Since this bulky residue cannot pass through the loop, only one homodimer (2·2) is formed in apolar solvents, for steric reasons, in which the two alkenyl residues penetrate the two macrocyclic loops. Covalent connection of these alkenyl groups by olefin metathesis followed by hydrogenation creates compounds 3, which consist of molecules with hitherto unknown topology. Their molecular structure was confirmed by 1HNMR spectroscopy and ESIMS, and for one example by single-crystal X-ray analysis.