1073974-16-9

Basic information

• Product Name: S-p-methoxyphenyl N-p-bromophenylthiocarbamate
• CAS NO: 1073974-16-9
• Molecular Weight: 338.225
• Mol File: 1073974-16-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: S-p-methoxyphenyl N-p-bromophenylthiocarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: S-p-methoxyphenyl N-p-bromophenylthiocarbamate(1073974-16-9)
• EPA Substance Registry System: S-p-methoxyphenyl N-p-bromophenylthiocarbamate(1073974-16-9)

Safety Data

• Hazardous Substances Data: 1073974-16-9(Hazardous Substances Data)

Upstream product

• 696-63-9 4-Methoxybenzenethiol 
• 2493-02-9 4-bromophenyl isocyanate 

Downstream Products

• 13114-92-6 1-(4-bromophenyl)-3-phenyl-urea 

Relevant articles and documents

Kinetics and mechanism of the anilinolysis of S-aryl N-arylthiocarbamates in acetonitrile

The aminolysis reactions of S-aryl N-arylthiocarbamates (YC 6H4NH-C(=O)-SC6H4Z, 1) with anilines in acetonitrile are studied. The reaction rates are more influenced by the nucleophilicity of the nucleophile than the nucleofugality of the leaving group, but the change In the effective charge from reactants to the TS for formation of the tetrahedral intermediate is slightly greater in the leaving group (βz from-0.07 to -0.14) than In the nucleophile (βx = 0.04-0.12). The magnitude of the Broensted coefficients are in the range of values that are consistent for a stepwise mechanism with rate-limiting formation of the zwitterionic tetrahedral intermediate. Signs of cross-interaction constants, ρxy (>0), ρxz (>0) and ρyz (0), are all consistent with a stepwise mechanism. It Is concluded that the change of the amine from benzylamines to anilines causes a shift of the aminolysis mechanism from a concerted to a stepwise process. Copyright