107399-02-0Relevant articles and documents
NEW METHODS AND REAGENTS IN ORGANIC SYNTHESIS. 62 TRIMETHYLSILYLDIAZOMETHANE: A CONVENIENT REAGENT FOR THE PREPARATION OF ACYLSILANES
Aoyama, Toyohiko,Shioiri, Takayuki
, p. 2005 - 2006 (1986)
The lithium salt of trimethylsilyldiazomethane smoothly reacts with alkyl halides to give α-trimethylsilyldiazoalkanes which are easily oxidized with m-chloroperbenzoic acid (m-CPBA), giving the corresponding acylsilanes (α-ketosilanes) in good yields.