Tetrahedron Letters p. 2005 - 2006 (1986)
Update date:2022-08-11
Topics:
Aoyama, Toyohiko
Shioiri, Takayuki
The lithium salt of trimethylsilyldiazomethane smoothly reacts with alkyl halides to give α-trimethylsilyldiazoalkanes which are easily oxidized with m-chloroperbenzoic acid (m-CPBA), giving the corresponding acylsilanes (α-ketosilanes) in good yields.
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Doi:10.1039/b516924k
(2006)Doi:10.1016/S0040-4020(97)00699-6
(1997)Doi:10.1002/chem.201703686
(2018)Doi:10.1021/acs.jnatprod.7b00328
(2017)Doi:10.1002/cctc.202000349
(2020)Doi:10.1007/BF01303602
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