107399-03-1

Basic information

• Product Name: (1-Diazo-3-phenyl-propyl)-trimethyl-silane
• Synonyms: (1-Diazo-3-phenyl-propyl)-trimethyl-silane
• CAS NO: 107399-03-1
• Molecular Weight: 218.374
• Mol File: 107399-03-1.mol

Chemical Properties

• CAS DataBase Reference: (1-Diazo-3-phenyl-propyl)-trimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: (1-Diazo-3-phenyl-propyl)-trimethyl-silane(107399-03-1)
• EPA Substance Registry System: (1-Diazo-3-phenyl-propyl)-trimethyl-silane(107399-03-1)

Safety Data

• Hazardous Substances Data: 107399-03-1(Hazardous Substances Data)

Upstream product

• 84645-45-4 lithio(trimethylsilyl)diazomethane 
• 103-63-9 1-phenyl-2-bromoethane 

Downstream Products

• 53304-24-8 Trimethyl-((E)-3-phenyl-propenyl)-silane 
• 58541-15-4 trans-1-(trimethylsilyl)-3-phenyl-1-propene 
• 73727-44-3 (Z)-trimethyl(3-phenylprop-1-en-1-yl)silane 
• 61157-31-1 3-phenylpropionyltrimethylsilane 

Relevant articles and documents

TRIMETHYLSILYLDIAZOMETHANE: A CONVENIENT REAGENT FOR THE PREPARATION OF (E)-1-TRIMETHYLSILYL-1-ALKENES

The cuprous chloride-catalyzed decomposition of α-trimethylsilyldiazoalkanes gives (E)-1-trimethylsilyl-1-alkenes in high yields.

NEW METHODS AND REAGENTS IN ORGANIC SYNTHESIS. 62 TRIMETHYLSILYLDIAZOMETHANE: A CONVENIENT REAGENT FOR THE PREPARATION OF ACYLSILANES

The lithium salt of trimethylsilyldiazomethane smoothly reacts with alkyl halides to give α-trimethylsilyldiazoalkanes which are easily oxidized with m-chloroperbenzoic acid (m-CPBA), giving the corresponding acylsilanes (α-ketosilanes) in good yields.