53304-24-8Relevant academic research and scientific papers
TRIMETHYLSILYLDIAZOMETHANE: A CONVENIENT REAGENT FOR THE PREPARATION OF (E)-1-TRIMETHYLSILYL-1-ALKENES
Aoyama, Toyohiko,Shioiri, Takayuki
, p. 6295 - 6296 (2007/10/02)
The cuprous chloride-catalyzed decomposition of α-trimethylsilyldiazoalkanes gives (E)-1-trimethylsilyl-1-alkenes in high yields.
Silicon-directed Elimination from β-Trimethylsilyl Sulphoxides and the Regiospecific Synthesis of Olefins
Ochiai, Masahito,Tada, Shin-ichi,Sumi, Kenzo,Fujita, Eiichi
, p. 281 - 282 (2007/10/02)
The regiospecific formation of olefins by the thermal elimination of sulphenic acid from β-trimethylsilyl sulphoxides followed by protodesilylation is reported and the effect of the trimethylsilyl group on thermal elimination is discussed.
