107399-13-3

Basic information

• Product Name: 3-benzoxypropyl trimethylsilyl ketone
• Synonyms: 3-benzoxypropyl trimethylsilyl ketone
• CAS NO: 107399-13-3
• Molecular Weight: 236.386
• Mol File: 107399-13-3.mol

Chemical Properties

• CAS DataBase Reference: 3-benzoxypropyl trimethylsilyl ketone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-benzoxypropyl trimethylsilyl ketone(107399-13-3)
• EPA Substance Registry System: 3-benzoxypropyl trimethylsilyl ketone(107399-13-3)

Safety Data

• Hazardous Substances Data: 107399-13-3(Hazardous Substances Data)

Downstream Products

• 1254704-23-8 2-(2-phenoxyethyl)-3-phenyl-1-(trimethylsilyl)pent-4-en-1-one 

Relevant articles and documents

Efficient Generation and Synthetic Applications of Alkyl-Substituted Siloxycarbenes: Suppression of Norrish-Type Fragmentations of Alkanoylsilanes by Triplet Energy Transfer

Acylsilanes have been known to undergo isomerization to siloxycarbenes under photoirradiation and the thus generated carbenes can be utilized for various synthetic reactions. But this carbene formation is not necessarily efficient with some alkanoylsilanes because Norrish-type fragmentations compete, which limit the synthetic utility of alkanoylsilanes as carbene precursors. In this study, generation of siloxycarbenes from alkanoylsilanes by visible-light-induced energy transfer was examined by using an Ir complex, [Ir{dF(CF3)ppy}2(dtbpy)]PF6, and was successfully applied to the C?C coupling reactions with boronic esters or aldehydes. This methodology efficiently suppressed undesired Norrish-type reactions and broadened synthetic utility of alkanoylsilanes.

NEW METHODS AND REAGENTS IN ORGANIC SYNTHESIS. 62 TRIMETHYLSILYLDIAZOMETHANE: A CONVENIENT REAGENT FOR THE PREPARATION OF ACYLSILANES

The lithium salt of trimethylsilyldiazomethane smoothly reacts with alkyl halides to give α-trimethylsilyldiazoalkanes which are easily oxidized with m-chloroperbenzoic acid (m-CPBA), giving the corresponding acylsilanes (α-ketosilanes) in good yields.