107487-09-2Relevant academic research and scientific papers
Synthesis of (Diethoxyphosphoryl)acetonitrile Oxide and Its Cycloaddition to Olefins. Synthetic Applications to 3,5-Disubstituted 2-Isoxazolines
Tsuge, Otohiko,Kanemasa, Shuji,Suga, Hiroyuki,Nakagawa, Norihiko
, p. 2463 - 2474 (2007/10/02)
(Diethoxyphosphoryl)acetonitrile oxide undergoes regioselective cycloaddition to olefins leading to 3--2-isoxazolines or -isoxazole.The phosphorus-stabilized carbanions generated by deprotonation of the cycloadducts can be util
SYNTHESIS OF A NEW PHOSPHOROUS-FUNCTIONALIZED NITRILE OXIDE, Α-(DIETHYLPHOSPHONO)ACETONITRILE OXIDE, AND CYCLOADDITION LEADING TO 3-(DIETHYLPHOSPHONOMETHYL)-Δ2-ISOXAZOLINES
Tsuge, Otohiko,Kanemasa, Shuji,Suga, Hiroyuki
, p. 183 - 186 (2007/10/02)
Cycloaddition of α-(diethylphosphono)acetonitrile oxide, a new phosphorous-functionalized nitrile oxide, leads to 3-phosphonomethyl-Δ2-isoxazolines which are useful as Δ2-isoxazoline unit-introducing reagents.
