107487-23-0

Basic information

• Product Name: (-)-α-naphthylphenylmethylsilyl t-butylphenylphosphinite
• CAS NO: 107487-23-0
• Molecular Weight: 428.586
• Mol File: 107487-23-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-α-naphthylphenylmethylsilyl t-butylphenylphosphinite(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-α-naphthylphenylmethylsilyl t-butylphenylphosphinite(107487-23-0)
• EPA Substance Registry System: (-)-α-naphthylphenylmethylsilyl t-butylphenylphosphinite(107487-23-0)

Safety Data

• Hazardous Substances Data: 107487-23-0(Hazardous Substances Data)

Upstream product

• 98976-30-8 tert-Butylphenylphosphine oxide 
• 960-82-7 S(-)-methyl-α-naphthyl-phenyl-chlorosilane 
• 29949-69-7 tert-butylchlorophenylphosphane 
• 3554-09-4 C₁₇H₁₅OSi^(1-)*K⁽¹⁺⁾ 

Downstream Products

• 107487-33-2 naphtylphenylmethylsilyl t-butylphenylselenophosphinate 
• 107487-28-5 C₂₇H₂₉OPSSi 
• 4923-86-8 t-butyl(phenyl)phosphinic acid 
• 107487-26-3 α-naphtylphenylmethylsilyl t-butylphenyl-phosphinate 

Relevant articles and documents

OPTICALLY ACTIVE TRIORGANOSILYL ESTERS OF PHOSPHORUS. SYNTHESIS AND STRUCTURE

We report this synthesis of the first optically active silyl esters of phosphorus having two centres of chirality : one on silicon and the other on phosphorus.Compounds are obtained of general formula : t-BuPhP(X)YSiαNpPhMe X,Y=O, O(1); S, O(2); Se, O(3); S, S(4); doublet, O(5) including 1 and 3 with optical activity located on Si, 2 and 5 with the activity on Si or P and on both these centres, 4 only racemic.Absolute configurations are determined. 31P and 29Si NMR spectra of these models and their trimethylsilyl analogues are reported.The triorganosilyl group is always preferentially bound to phosphorus through oxygen atom.Surprisingly, diastereotopic NMR chemical shifts exclude the fast 1,3 migration in esters 1 and 4. 29Si NMR spectra correspond to a tetracoordinate silicon atom.