1075183-41-3Relevant academic research and scientific papers
Lewis acid catalyzed [1,3]-sigmatropic rearrangement of vinyl aziridines
Brichacek, Matthew,Lee, Dongeun,Njardarson, Jon T.
supporting information; scheme or table, p. 5023 - 5026 (2009/05/31)
(Chemical Equation Presented) This paper details the copper-catalyzed ring expansion of vinyl aziridines to 3-pyrrolines. Broad substrate scope (24 examples) using tosyl-and phthalimide-protected vinyl aziridine substrates is observed. Cu(hfacac)2/s
PRODUCTION OF 2,5-DIHYDROFURANS AND ANALOGOUS COMPOUNDS
-
Page/Page column 16, (2008/06/13)
Vinyl oxiranes are rearranged to 2,5-dihydrofuran using catalyst (III) or (IV). The 2,5-dihydrofuran can be reduced to tetrahydrofuran. 3,4-Epoxy-l-butene substrate is converted to 2,5-dihydrofuran which in turn is converted to tetrahydrofuran. Substrate
