1075183-25-3Relevant academic research and scientific papers
The Divergent Synthesis of Nitrogen Heterocycles by Rhodium(I)-Catalyzed Intermolecular Cycloadditions of Vinyl Aziridines and Alkynes
Feng, Jian-Jun,Lin, Tao-Yan,Zhu, Chao-Ze,Wang, Huamin,Wu, Hai-Hong,Zhang, Junliang
, p. 2178 - 2181 (2016/03/08)
Catalyst-controlled divergent intermolecular cycloadditions of vinylaziridines with alkynes have been developed. By using [Rh(NBD)2]BF4 as the catalyst, a [3 + 2] cycloaddition reaction was achieved with broad substrate scope and high stereoselectivity under mild reaction conditions. Moreover, the chirality of vinylaziridines can be completely transferred to the [3 + 2] cycloadducts. When the catalyst was changed to [Rh(η6-C10H8) (COD)]SbF6, the alternative [5 + 2] cycloadducts were selectively formed under otherwise identical conditions.
Lewis acid catalyzed [1,3]-sigmatropic rearrangement of vinyl aziridines
Brichacek, Matthew,Lee, Dongeun,Njardarson, Jon T.
supporting information; experimental part, p. 5023 - 5026 (2009/05/31)
(Chemical Equation Presented) This paper details the copper-catalyzed ring expansion of vinyl aziridines to 3-pyrrolines. Broad substrate scope (24 examples) using tosyl-and phthalimide-protected vinyl aziridine substrates is observed. Cu(hfacac)2/s
