1075211-18-5Relevant academic research and scientific papers
Synthesis of the mixed acetal segment of S-glyceroplasmalopsychosine
Parhi, Ajit K.,Mootoo, David R.,Franck, Richard W.
scheme or table, p. 9821 - 9827 (2009/04/03)
In this report the concept of converting carbohydrate to non-carbohydrate asymmetric molecules has been successfully exploited. The mixed acetal segment of glyceroplasmalopsychosine, a novel glycolipid, has been synthesized in a stereospecific manner using two simple sugar units. The glycosidation reaction between these two monosaccharides ensured the correct acetal stereocenter of the target molecule. Either olefin metathesis or heterogeneous Wittig reactions were used for constructing the long aliphatic chain of glyceroplasmalopsychosine.
