1075256-83-5Relevant academic research and scientific papers
Formation of a bridging-imido d6 rhodium compound by nitrene capture. Insertion and cycloaddition reactions
Tejel, Cristina,Ciriano, Miguel A.,Jimenez, Sonia,Passarelli, Vincenzo,Lopez, Jose A.
, p. 10220 - 10222 (2008)
The first d6 rhodium imido complex, [{(C5Me 5)Rh(μ-NSO2C6H4Me-p)} 2] (2), has been obtained from the reaction of [(C5Me 5)Rh(C2H4)2] with chloramine-T. Carbon monoxide inserts into the N-Rh bonds in 2 to give the dinuclear ureylene complex [(C5Me5)Rh(μ-{(Ts)N-CO-N(Ts)}Rh(CO)(C 5Me5)], while the azide C6F5N 3 adds to 2 to give the mononuclear tetrazene complex [(C 5Me5)Rh{(p-MeC6H4SO 2)N4(C6F5)}].
