107536-34-5Relevant academic research and scientific papers
The Aryne [2,3] Stevens Rearrangement
Roy, Tony,Thangaraj, Manikandan,Kaicharla, Trinadh,Kamath, Rupa V.,Gonnade, Rajesh G.,Biju, Akkattu T.
, p. 5428 - 5431 (2016)
Arynes are employed in the transition-metal-free and mild [2,3] Stevens rearrangement of tertiary allylic amines for the synthesis of functionalized homoallylic amines in moderate to good yield with a broad substrate scope. The key nitrogen ylide intermediate was generated by the N-arylation of allyl amines using arynes. Moreover, the reaction of chiral allyl amines with arynes resulted in the enantiospecific synthesis of homoallylic amines. In addition, preliminary studies on the [1,2] Stevens rearrangement is also presented.
METALLIC COPPER CATALYSIS OF N-ARYLATION OF AMINES BY TRIARYLBISMUTH DIACYLATES
Barton, Derek H. R.,Finet, Jean-Pierre,Khamsi, Jamal
, p. 3615 - 3618 (2007/10/02)
The N-arylation of aliphatic and aromatic amines by triarylbismuth diacylates under neutral conditions is strongly catalysed by copper powder at room temperature.
