107550-83-4

Basic information

• Product Name: (2E,4E)-hexa-2,4-diene-1,6-diol
• CAS NO: 107550-83-4
• Molecular Formula: C₆H₁₀O₂
• Molecular Weight: 114.1424
• Mol File: 107550-83-4.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 273.1°C at 760 mmHg
• Flash Point: 137.1°C
• Density: 1.039g/cm³
• Vapor Pressure: 0.000751mmHg at 25°C
• Refractive Index: 1.513
• CAS DataBase Reference: (2E,4E)-hexa-2,4-diene-1,6-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (2E,4E)-hexa-2,4-diene-1,6-diol(107550-83-4)
• EPA Substance Registry System: (2E,4E)-hexa-2,4-diene-1,6-diol(107550-83-4)

Safety Data

• Hazardous Substances Data: 107550-83-4(Hazardous Substances Data)

Upstream product

• 6032-74-2 diethyl (2E,4E)-2,4-hexadienedioate 
• 60-29-7 diethyl ether 
• 3031-68-3 Hexa-2,4-diyne-1,6-diol 
• 628-16-0 hexa-1,5-diyne 
• 3588-17-8 trans,trans-muconic acid 
• 1119-43-3 (E,E)-hexa-2,4-dienedioic acid dimethyl ester 
• 58823-55-5 (E,E)-muconic acid dichloride 
• 3588-17-8 (2E,4E)-2,4-hexadienedioic acid 

Downstream Products

• 109669-50-3 (2E,4E)-1,6-bis(benzyloxy)hexa-2,4-diene 
• 150919-19-0 (2E,4E)-6-(tert-Butyl-diphenyl-silanyloxy)-hexa-2,4-dien-1-ol 
• 929198-06-1 C₃₈H₄₆O₂Si₂ 
• 2117-21-7 trans-1,4-Bis-(trimethylsiloxymethyl)-cyclohexan 
• 3236-48-4 trans-1,4-Cyclohexanedimethanol 
• 3236-47-3 (1s,4s)-cyclohexane-1,4-diyldimethanol 
• 153885-97-3 (5Z,7E,9E)-11-[2-(4-Chloro-phenoxy)-acetoxy]-undeca-5,7,9-trienoic acid methyl ester 
• 153885-89-3 (5Z,7E,9E)-11-(2-Phenoxy-acetoxy)-undeca-5,7,9-trienoic acid methyl ester 
• 153885-87-1 (4-Chloro-phenoxy)-acetic acid (2E,4E)-6-oxo-hexa-2,4-dienyl ester 

Relevant articles and documents

Stereospecific Photochemical Cyclization of Azidoquinone with E,E- and Z,Z-Dienes. Application to the Synthesis of an Importent Precursor toward Mitomycins

Photochemical reaction of 5-azido-2-methoxy-3-methyl-1,4-benzoquinone with cis,cis-2,4-hexadien-1,6-diol derivatives stereoselectively affords the corresponding 2,3-dihydroindolquinone, which possesses trans configuration at 2,3-position and vinylic double bond preserves the original stereochemistry of the diene.It is efficiently converted to a key precursor in mitomycin synthesis.

Low-pressure synthesis of cyclohexanedimethanol and derivatives

The invention is directed to a process for preparing a 1,4-disubstituted cyclohexane compound of formula (I): where A is —OH, —OR, Br, or Cl; and R is a silyl group, a hydrocarbyl group, or an acyl group having 1 to 12 carbon atoms. The process includes the steps of reacting ethylene with a (2E,4E)-hexa-2,4-diene compound to produce a 3,6-disubstituted cyclohex-1-ene compound, and hydrogenating the 3,6-disubstituted cyclohex-1-ene compound to yield the 1,4-disubstituted cyclohexane compound of formula (I).

A novel catalytic asymmetric route towards skipped dienes with a methyl-substituted central stereogenic carbon

A highly efficient method for the enantioselective synthesis of 1,4-dienes (skipped dienes) with a methyl-substituted central stereogenic carbon using copper-catalysed asymmetric allylic alkylation of diene bromides was developed. Excellent regio- and enantioselectivity (up to 97 : 3 SN2′/ SN2 ratio and 99% ee) were achieved with broad substrate scope. The Royal Society of Chemistry 2013.