Cas 107556-17-2,(C5H5)2Zr(CH2P(C6H5)2)2RhH(P(C6H5)3)

107556-17-2

Post Buying Request

Basic information

Product Name: (C₅H₅)2Zr(CH₂P(C₆H₅)2)2RhH(P(C₆H₅)3)
Synonyms: (C₅H₅)2Zr(CH₂P(C₆H₅)2)2RhH(P(C₆H₅)3)
CAS NO:107556-17-2
Molecular Formula:
Molecular Weight: 986.042
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (C₅H₅)2Zr(CH₂P(C₆H₅)2)2RhH(P(C₆H₅)3)(CAS DataBase Reference)
NIST Chemistry Reference: (C₅H₅)2Zr(CH₂P(C₆H₅)2)2RhH(P(C₆H₅)3)(107556-17-2)
EPA Substance Registry System: (C₅H₅)2Zr(CH₂P(C₆H₅)2)2RhH(P(C₆H₅)3)(107556-17-2)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 107556-17-2(Hazardous Substances Data)

Suppliers
Usage
Upstream product
Downstream Products
Article

107556-17-2 Suppliers

Recommended suppliers

107556-17-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 107556-17-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,7,5,5 and 6 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 107556-17:
(8*1)+(7*0)+(6*7)+(5*5)+(4*5)+(3*6)+(2*1)+(1*7)=122
122 % 10 = 2
So 107556-17-2 is a valid CAS Registry Number.

107556-17-2Upstream product

18284-36-1 hydridotetakis(triphenylphosphine)rhodium(I)

107556-17-2Downstream Products

107556-17-2Relevant academic research and scientific papers

A ZIRCONIUM-RHODIUM HYDRIDO COMPLEX, Cp2Zr(CH2PPh2)2RhH(PPh3), AS CATALYST FOR THE HYDROFORMYLATION OF 1-HEXENE

Choukroun, R.,Iraqi, A.,Gervais, D.

, p. C60 - C62 (1986)

The early-late transition metal complex Cp2Zr(CH2PPh2)2RhH(PPh3) has been prepared by the reaction of the zirconium diphosphine Cp2Zr(CH2PPh2)2 with the hydride RhH(PPh3)4.Its behaviour as a catalyst for the hydroformylation of 1-hexene under mild conditions is compared with that of related species.

A semibridging hydrido zirconium-rhodium complex: A possible way to catalytic hydrogen transfer on d0-d8 systems

Choukroun, Robert,Iraqi, Ahmed,Gervais, Danièle,Daran, Jean-Claude,Jeannin, Yves

, p. 1197 - 1201 (2008/10/08)

Zirconium-rhodium complexes are studied with the aim of generating a zirconium-hydrogen bond by rhodium-mediated activation of dihydrogen in order to obtain highly selective catalytic synthesis. By reaction of the bis(phosphinomethyl) complex Cp2Zr(CH2PPh2)2 on Rh(H)(PPh3)4 we get the bimetallic hydride Cp2Zr(CH2PPh2)2Rh(H)(PPh 3) (3), which was structurally characterized (crystal system monoclinic, space group PZ1/n, a = 12.189 (2) ?, b = 21.054 (3) ?, c = 17.587 (2) ?, β = 98.67 (1)°, Z = 4). The most remarkable structural features of 3 are the trans chelating arrangement of the bis[(diphenylphosphino)methyl]zirconium on rhodium together with pentacoordination around zirconium due to a strong interaction of Zr on the Rh-H bond with a Zr?H distance of 2.28 (5) ?. The bimetallic system is an efficient precursor for selective catalytic hydroformylation of 1-hexene.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 107556-17-2