A ZIRCONIUM-RHODIUM HYDRIDO COMPLEX, Cp2Zr(CH2PPh2)2RhH(PPh3), AS CATALYST FOR THE HYDROFORMYLATION OF 1-HEXENE

DOI: 10.1016/0022-328X(86)80268-6

Source and publish data:

Journal of Organometallic Chemistry p. C60 - C62 (1986)

Update date:2022-08-05

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Authors:

Choukroun, R.

Iraqi, A.

Gervais, D.

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Article abstract of DOI:10.1016/0022-328X(86)80268-6

The early-late transition metal complex Cp2Zr(CH2PPh2)2RhH(PPh3) has been prepared by the reaction of the zirconium diphosphine Cp2Zr(CH2PPh2)2 with the hydride RhH(PPh3)4.Its behaviour as a catalyst for the hydroformylation of 1-hexene under mild conditions is compared with that of related species.

Full text of DOI:10.1016/0022-328X(86)80268-6

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