1075709-09-9Relevant articles and documents
Tea leaf perfumery precursor glucoside and synthesizing method thereof
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, (2020/07/02)
The invention relates to a tea leaf perfumery precursor glucoside and a synthesizing method thereof. The synthesizing method comprises the following steps of synthesizing ten glucosides including aromatic alcohol ( alkanol )-beta -D-glucosides and aromatic alcohol (alkanol )-beta -D-primrose indicans. The synthesizing method disclosed by the invention is a glucoside synthesizing method which is good in selectivity, high in production rate and low in cost.
A divergent approach to the synthesis of simplexides and congeners via a late-stage olefin cross-metathesis reaction
Li, Jiakun,Li, Wei,Yu, Biao
, p. 4971 - 4974 (2013/08/23)
Simplexides constitute a unique group of immunosuppressive glycolipids that demonstrate antiproliferative activities against activated T-cell lymphocytes via a unique non-cytotoxic inhibition. To investigate the structure-activity relationship of the varied long-chain secondary alcohols on simplexides, we developed an efficient and divergent route to the synthesis of simplexides and congeners, taking advantage of a late-stage olefin cross-metathesis reaction.
NAP ether mediated intramolecular aglycon delivery: A unified strategy for 1,2-cis-glycosylation
Ishiwata, Akihiro,Munemura, Yuichi,Ito, Yukishige
supporting information; experimental part, p. 4250 - 4263 (2009/04/10)
A methodology directed towards the stereoselective construction of 1,2-cis-glycosides through naphthylmethyl (NAP) ether mediated intramolecular aglycon derivery (IAD) has been developed. Stereospecific constructions of various 1,2-cis linkages, as in β-mannopyrano-, β-arabinofurano-, and α-glucopyranosides, were achieved through NAP-IAD. This methodology was successfully applied to the synthesis of Glcα(1→2)- Glcα(1→3)-Glcα(1→3)Man (Glc3Man1), the nonreducing terminal structure of the tetradecasaccharide Glc 3Man9GlcNAc2, a common precursor of all N-linked glycans. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.