1206803-44-2

Upstream product

• 108-24-7 acetic anhydride 
• 1055325-21-7 p-methoxyphenyl 2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 1259298-27-5 4-methoxyphenyl 2,3,4-tri-O-benzyl-6-O-tert-butyldiphenylsilyl-β-D-glucopyranoside 
• 1075709-09-9 1-O-p-methoxyphenyl 6-O-tert-butyldiphenylsilyl-β-D-glucopyranose 
• 3150-20-7 4-methoxyphenyl β-D-glucopyranoside 
• 150-76-5 4-methoxy-phenol 
• 2872-65-3 p-methoxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside 
• 604-69-3 β-D-glucose pentaacetate 

Downstream Products

• 88567-49-1 6-O-acetyl-2,3,4-tri-O-benzyl-D-glucopyranose 
• 1448001-78-2 C₃₉H₆₈O₁₁ 
• 1448001-59-9 2,3-O-acetyl-6-O-benzyl-4-O-(2,3,4-tri-O-benzyl-6-O-acetyl-β-D-glucopyranosyl)-β-D-galactopyranosyl N-phenyltrifluoroacetimidate 
• 1448001-58-8 p-methoxyphenyl 2,3-O-acetyl-6-O-benzyl-4-O-(2,3,4-tri-O-benzyl-6-O-acetyl-β-D-glusopyranosyl)-β-D-galactopyranoside 

Relevant academic research and scientific papers

A divergent approach to the synthesis of simplexides and congeners via a late-stage olefin cross-metathesis reaction

Simplexides constitute a unique group of immunosuppressive glycolipids that demonstrate antiproliferative activities against activated T-cell lymphocytes via a unique non-cytotoxic inhibition. To investigate the structure-activity relationship of the varied long-chain secondary alcohols on simplexides, we developed an efficient and divergent route to the synthesis of simplexides and congeners, taking advantage of a late-stage olefin cross-metathesis reaction.

Highly efficient and mild method for regioselective de-O-benzylation of saccharides by Co2(CO)8-Et3SiH-CO reagent system

[Chemical equation presented] A highly efficient and mild method for the de-O-benzylation of protected saccharides was developed by transforming terminal benzyl ethers Into silyl ethers using Co2(CO)8-Et 3SIH under 1 atm of CO. The method was successfully used for the de-O-benzylatlon of perbenzylated monosaccharides with various anomerlc protecting groups, as well as natural disaccharldes and trisaccharides such as sucrose, raffinose, and melezltose In good yields (>80%).