107613-10-5Relevant academic research and scientific papers
A new entry to enantiopure polysubstituted cyclopropanes: Stereoselective denitrogenation of sulfinylpyrazolines under Yb(OTf)3 catalysis
Ruano, Jose L. Garcia,Peromingo, M. Teresa,Martin, M. Rosario,Tito, Amelia
, p. 3295 - 3298 (2006)
Chemoselective and completely stereoselective denitrogenation of optically pure pyrazolines, derived from 3-sulfinylfuran-2(5H)-ones, into cyclopropanes can be achieved under substoichiometric Yb(OTf)3 catalysis. Reactions evolve in almost quan
1,3-Dipolar cycloadditions of diazoalkanes to activated sulfoxides: Influence of Lewis acids
Garcia Ruano, Jose L.,Peromingo, M. Teresa,Alonso, Marina,Fraile, Alberto,Martin, M. Rosario,Tito, Amelia
, p. 8942 - 8947 (2007/10/03)
The reactions of diazomethane and diazoethane with (S)-3-p- tolylsulfinylfuran-2(5H)-one (3) and its 4-methyl derivative (4) have been studied. The sulfinyl group was able to completely control the π-facial selectivity of all these reactions, which decrea
AN EFFICIENT SYNTHESIS OF CHIRAL 2-(p-TOLYLSULFINYL)-2-BUTENOLIDES
Holton, Robert A.,Kim, Hyeong-Baik
, p. 2191 - 2194 (2007/10/02)
A high yield, two-step synthesis of enantiomerically pure 2-(p-tolylsulfinyl)-2-butenolides has been developed.The method is applicable to the preparation of butenolides having a variety of substituents in the 3-position.
