107622-21-9Relevant academic research and scientific papers
Nucleophilic Addition to Olefins. 16. Unusual Substituent Effects in the Reaction of Amines with β-Nitrostyrenes. Solvent Effect on Intrinsic Rate Constants
Bernasconi, Claude F.,Renfrow, Richard A.,Tia, Paul R.
, p. 4541 - 4549 (1986)
A kinetic study of the addition of piperidine and morpholine to β-nitrostyrene in water and in 70percent Me2SO-30percent water at 20 deg C and of piperidine to 4-NO2-, 4-CN-, 3-Cl-, 4-Br-, 4-OMe-, and 4-NMe2-substituted β-nitrostyrenes in water at 20 deg
Kinetic study on michael-type reactions of β-nitrostyrenes with cyclic secondary amines in acetonitrile: Transition-state structures and reaction mechanism deduced from negative enthalpy of activation and analyses of LFERs
Um, Ik-Hwan,Kang, Ji-Sun,Park, Jong-Yoon
supporting information, p. 5604 - 5610 (2013/07/26)
A kinetic study is reported for the Michael-type reactions of X-substituted β-nitrostyrenes (1a-j) with a series of cyclic secondary amines in MeCN. The plots of pseudo-first-order rate constant kobsd vs [amine] curve upward, indicating that th
