Nucleophilic Addition to Olefins. 16. Unusual Substituent Effects in the Reaction of Amines with β-Nitrostyrenes. Solvent Effect on Intrinsic Rate Constants

Article abstract of DOI:10.1021/ja00275a047

A kinetic study of the addition of piperidine and morpholine to β-nitrostyrene in water and in 70percent Me2SO-30percent water at 20 deg C and of piperidine to 4-NO2-, 4-CN-, 3-Cl-, 4-Br-, 4-OMe-, and 4-NMe2-substituted β-nitrostyrenes in water at 20 deg