107624-25-9

Basic information

• Product Name: 2-(benzyloxymethyl)pyridine
• Synonyms: 2-(benzyloxymethyl)pyridine
• CAS NO: 107624-25-9
• Molecular Weight: 199.252
• Mol File: 107624-25-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(benzyloxymethyl)pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(benzyloxymethyl)pyridine(107624-25-9)
• EPA Substance Registry System: 2-(benzyloxymethyl)pyridine(107624-25-9)

Safety Data

• Hazardous Substances Data: 107624-25-9(Hazardous Substances Data)

Upstream product

• 1007-49-4 2-pyridylmethyl acetate 
• 100-39-0 benzyl bromide 
• 4377-33-7 2-chloromethylpyridine 
• 586-98-1 2-Hydroxymethylpyridine 
• 100-44-7 benzyl chloride 

Downstream Products

• 20609-08-9 2-phenyl-1-(pyridin-2-yl)ethan-1-ol 

Relevant articles and documents

Development of dipyridine-based coordinative polymers for reusable heterogeneous catalysts

Poly(di(pyridin-2-yl)methyl acrylate) (PDPyMA), which was obtained by the free radical polymerization of designed coordinative monomer of di(pyridin-2-yl)methyl acrylate, is able to coordinate with various metal ions to form heterogeneous catalysts for diverse catalytic reactions. The Pd and Cu complexes supported by PDPyMA were developed for the heterogeneous Suzuki-Miyaura reaction and Friedel-Crafts alkylation, respectively. The PDPyMA-based catalysts showed no significant decline of reactivity after five times recycling. However, the hydrolysis of the PDPyMA backbone under alkaline conditions limited the catalytic efficiency of this heterogeneous catalyst so that the coordinative monomer was redesigned as 1,1-di(pyridine-2-yl)-2-(4-vinylphenyl)ethan-1-ol and then 2,2′-(1-methoxy-2-(4-vinylphenyl)ethane-1,1-diyl)dipyridine (MVPhDPy). With copolymerization of N-isopropyl acrylamide (NIPAM), the efficiency of polymer-based heterogeneous catalysts could be further raised, demonstrated by the increased turn over number in the Suzuki-Miyaura reaction, which approached 5,260 by using the catalyst formed from poly(MVPhDPy-co-NIPAM) and Pd(OAc)2. poly(MVPhDPy-co-NIPAM) copolymer, therefore, could be a versatile platform to support different metal ions for various heterogeneous catalytic reactions.

Synthesis of alkyl heteryl ethers from acetates under interphase catalysis conditions in a liquid/solid system

The reaction of acetates of heterocyclic alcohols with alkyl halides in the two-phase catalytic system of solid KOH/C6H6/18-crown-6 at room temperature leads selectively to the formation of the corresponding heterocyclic ethers in 32-93% yield. 1998 Plenum Publishing Corporation.