107692-01-3Relevant academic research and scientific papers
Cobalt-Catalyzed Trifluoromethoxylation of Epoxides
Liu, Jie,Wei, Yongliang,Tang, Pingping
, p. 15194 - 15199 (2018)
A catalytic ring-opening reaction of epoxides by nucleophilic trifluoromethoxylation of trifluoromethyl arylsulfonate has been developed based on the use of a cobalt catalyst. This reaction provides an efficient, simple route for directly construction of a wide range of vicinal trifluoromethoxyhydrins under mild conditions. In addition, this method can convert terminal epoxides into target products with good chemo- and regioselectivity.
ALLYLATION OF GRIGNARD REAGENTS: ITS APPLICATION FOR THE SYNTHESIS OF (4E,7Z)-4,7-TRIDECADIENYL ACETATE, A SEX PHEROMONE OF POTATO TUBERWORM MOTH
Yadav, J. S.,Reddy, P. Satyanarayana
, p. 1119 - 1132 (2007/10/02)
Alkylmagnesium halides have been found to react with (Z)-4-benzyloxy-1-chloro-2-butene in presence of HMPA to produce a rearranged product 3-alkyl-4-benzyloxy-1-butene, while the absence of HMPA a normal product (Z)-1-alkyl-4-benzyloxy-2-butene resulted as the predominant product.Latter product has been utilized for the synthesis of (4E,7Z)-4,7-tridecadienyl acetate, a sex pheromone of potato tuberworm moth.
