107729-25-9Relevant academic research and scientific papers
Diozonolyses of Acyclic Conjugated Dienes in Methanol
Griesbaum, Karl,Zwick, Gerhard
, p. 229 - 243 (2007/10/02)
In the diozonolyses of isoprene (1a), 2-methyl-3-phenyl-1,3-butadiene (1b), 2,3-diphenyl-1,3-butadiene (26), and 2,3,4,5-tetramethyl-2,4-hexadiene (30) in methanol subsequent reactions of the primary cleavage products afforded abnormal products, which arose from cleavage of both the double bonds and the single bonds of the diene systems.In addition, the diozonolyses of 26 and 30 gave products, in which one of the double bonds of the respective diene system has been epoxidized.The mode of formation of the abnormal cleavage products has been elucidated by the ozonolysis of the intermediate products, viz. of α,β-unsaturated methoxyhydroperoxides and of α,β-unsaturated carbonyl compounds.
