107796-97-4

Basic information

• Product Name: (2S,3S)-(3-nonyloxiran-2-yl)methanol
• CAS NO: 107796-97-4
• Molecular Weight: 200.321
• Mol File: 107796-97-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (2S,3S)-(3-nonyloxiran-2-yl)methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-(3-nonyloxiran-2-yl)methanol(107796-97-4)
• EPA Substance Registry System: (2S,3S)-(3-nonyloxiran-2-yl)methanol(107796-97-4)

Safety Data

• Hazardous Substances Data: 107796-97-4(Hazardous Substances Data)

Upstream product

• 22104-81-0 (2E)-dodec-2-en-1-ol 
• 42778-95-0 ethyl (E)-dodec-2-enoate 
• 112-30-1 1-Decanol 
• 112-31-2 caprinaldehyde 

Relevant articles and documents

Asymmetric synthesis using diisopropyl tartrate modified (E)- and (Z)-crotylboronates: Preparation of the chiral crotylboronates and reactions with achiral aldehydes

Diisopropyl tartrate modified (E)- and (Z)-crotylboronates 2 and 3 are easily prepared with very high isomeric purity (≥98% E for 2; ≥99% Z for 3) via the metalation of (E)- and (Z)-2-butene with n-BuLi and KOtBu in THF followed by treatment of the (E)- a

An efficient synthesis of (-)-posticlure: The sex pheromone of Orgyia postica

An efficient multigram synthesis of (-)-posticlure, the first frans-epoxide sex pheromone found in Orgyia postica, from diethyl L-tartrate is described. The synthesis was completed in seven steps and 27 % overall yield. The synthetic strategy features double-Wittig olefination and a stereoselective one-pot conversion of diol to epoxide as the key steps. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

Synthesis of the optical antipodes of 4-alkyl-γ-lactones

Optical antipodes of 4-alkyl-γ-lactones 3 have been prepared by photochemical rearrangement of optically active α,β-epoxy diazomethyl ketones 1 in ethanol to give 4-hydroxy-alkenoates 2, followed by reduction of the alkene bond and subsequent lactonization.The required epoxy diazomethyl ketones 1 were obtained via the following sequence of reactions: alkylation of 2-propyn-1-ol, subsequent reduction to the alkenols 6, Sharpless epoxidation to 2,3-epoxy alcohols 7, oxidation to glycidic esters 8 and finally conversion to diazo ketones 1.The enantiomeric purities range from 84 to 100percent.