107811-53-0Relevant articles and documents
Synthesis and characterization of iron(III) complexes of diacetylbis-(4-methoxybenzoyl hydrazone)
Dey, Kamalendu,Bhattacharya, Prabir Kumar,Bandyopadhyay, Debasish,Chakraborty, Kartick,Mallick, Alok Kumar
, p. 529 - 534 (2007/10/02)
A few mono-and binuclear iron(III) complexes have been isolated by the reaction of diacetylbis(4-methoxybenzoyl hydrazone) H2dambhon with iron salts under varied reaction conditions.Some reactions of *4H2O, isolated in this study, with acetylacetone, pyridine, SnCl2 and PPh3 have been carried out which afforded new iron(III) complexes.The new complex , thus prepared, smoothly reacts with thiomethanol, N-trimethylsilyldimethylamine, benzyltrimethylsilane, and p-bis(trimethylsilylmethyl)benzene leading to the isolation of several new iron(III) and organoiron(III) compounds.The complexes are characterized on the basis of elemental analyses, molar conductance, molecular weight, magnetic susceptibilities and spectroscopic (electronic, IR and Moessbauer) data.The ligand H2 dambhon in these complexes functions as a NNOO donor either as a mono- or dianion or neutral ligand.