1078202-83-1

Basic information

• Product Name: 2-(4-methoxyphenyl)-2-(trimethylsilyl)ethenone
• Synonyms: 2-(4-methoxyphenyl)-2-(trimethylsilyl)ethenone
• CAS NO: 1078202-83-1
• Molecular Weight: 220.343
• Mol File: 1078202-83-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(4-methoxyphenyl)-2-(trimethylsilyl)ethenone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-methoxyphenyl)-2-(trimethylsilyl)ethenone(1078202-83-1)
• EPA Substance Registry System: 2-(4-methoxyphenyl)-2-(trimethylsilyl)ethenone(1078202-83-1)

Safety Data

• Hazardous Substances Data: 1078202-83-1(Hazardous Substances Data)

Upstream product

• 1078202-81-9 C₁₂H₁₆N₂O₂Si 
• 6832-17-3 2-diazo-1-(4-methoxyphenyl)ethanone 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 

Downstream Products

• 1078202-89-7 3-(4-methoxyphenyl)-1-phenyl-3-trimethylsilyl-1-trimethylsilyloxy-1,2-propanediene 
• 1078202-90-0 1,3-bis(4-methoxyphenyl)-3-trimethylsilyl-1-trimethylsilyloxy-1,2-propanediene 
• 1078202-92-2 3-(4-methoxyphenyl)-1-phenyl-1-triethylsilyloxy-3-trimethylsilyl-1,2-propanediene 
• 1078202-93-3 1,3-bis(4-methoxyphenyl)-1-triethylsilyloxy-3-trimethylsilyl-1,2-propanediene 

Relevant articles and documents

Aryl trialkylsilyl ketenes: Acid-catalyzed synthesis from 1-aryl-2-diazo-2-trialkylsilylethanones and their conversion into 3-silyl-1-silyloxyallenes

Aryl-substituted α-silyl α-diazo ketones are readily transformed into aryl silyl ketenes in the presence of a catalytic amount of triflic acid. Thus, a convenient method to prepare these silyl ketenes becomes available, which combines two steps, silylation of an aryl diazomethyl ketone and acid-induced Wolff rearrangement of the formed α-silyl α-diazo ketone, in a one-pot procedure. It appears that the trialkyl-ammonium salt, which is formed in the silylation step, can also catalyze the Wolff rearrangement, but distinctly more slowly than the proton acid. The silyl ketenes react smoothly with α-silyl α-diazo ketones to form 3-silyl-1-silyloxyallenes in fairly good yields. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.