107832-80-4

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 78177-42-1 C₁₇H₁₉O₂P 
• 119623-65-3 (E)-4-diphenylphosphinoyl-4-methoxybut-2-ene 

Downstream Products

• 125320-61-8 [(1E,3E)-4-(2-Allyloxy-phenyl)-3-methoxy-1-methyl-buta-1,3-dienyl]-trimethyl-silane 
• 125320-61-8 [(1E,3E)-4-(2-Allyloxy-phenyl)-3-methoxy-1-methyl-buta-1,3-dienyl]-trimethyl-silane 
• 125320-62-9 ((1E,3E)-4-{2-[((E)-But-2-enyl)oxy]-phenyl}-3-methoxy-1-methyl-buta-1,3-dienyl)-trimethyl-silane 
• 125320-62-9 ((1E,3E)-4-{2-[((E)-But-2-enyl)oxy]-phenyl}-3-methoxy-1-methyl-buta-1,3-dienyl)-trimethyl-silane 
• 125320-58-3 ((1E,3E)-3-Methoxy-1-methyl-4-phenyl-buta-1,3-dienyl)-trimethyl-silane 
• 125320-58-3 ((1E,3E)-3-Methoxy-1-methyl-4-phenyl-buta-1,3-dienyl)-trimethyl-silane 
• 125320-60-7 [(1E,3E)-3-Methoxy-4-(4-methoxy-phenyl)-1-methyl-buta-1,3-dienyl]-trimethyl-silane 
• 125320-60-7 [(1E,3E)-3-Methoxy-4-(4-methoxy-phenyl)-1-methyl-buta-1,3-dienyl]-trimethyl-silane 
• 125320-59-4 ((1E,3E)-3-Methoxy-1-methyl-4-p-tolyl-buta-1,3-dienyl)-trimethyl-silane 

Relevant academic research and scientific papers

PREPARATION OF 3-METHOXY-1-TRIMETHYLSILYL-1,3-DIENES USING A ONE-POT WITTIG-HORNER REACTION

3-Methoxy-1-trimethylsilyl-1,3-dienes, bearing a variety of substituents, have been conveniently prepared in a one-pot double quenching reaction of ylides derived from α-methoxyallyldiphenylphosphine oxides.

THE REACTIONS OF α-ALKOXYALLYLPHOSPHINE OXIDE YLIDES WITH SILICON, SULPHUR AND PHOSPHORUS ELECTROPHILES

Anions (2), derived from α-methoxyallylphosphine oxides (1), react with silicon, sulphur and phosphorus electrophiles in a highly regioselective fashion to give the products of γ-attack.