107839-76-9

Upstream product

• 300-57-2 allylbenzene 
• 421-50-1 1,1,1-trifluoro-2-propanone 

Downstream Products

• 122129-18-4 (1E)-1-phenyl-4-trifluoromethyl-1,4-pentadiene 
• 122129-48-0 (1E,3Z)-5,5,5-trifluoro-4-methyl-1-phenyl-1,3-pentadiene 
• 122129-14-0 (1E,3E)-5,5,5-trifluoro-4-methyl-1-phenyl-1,3-pentadiene 
• 107839-77-0 (2R*,5R*)-2-methyl-5-phenyl-2-(trifluoromethyl)tetrahydrofuran 
• 107839-77-0 (2R*,5S*)-2-methyl-5-phenyl-2-(trifluoromethyl)tetrahydrofuran 

Relevant academic research and scientific papers

Studies on Organic Fluorine Compounds. IL. The Ene Reaction of Trifluoroacetone

The ene reaction of 1,1,1-trifluoroacetone with various olefinic compounds proceeded in the presence of aluminum chloride at low temperature to give allylmethyl (trifluoromethyl)carbinols.Olefinic compounds with a terminal vinyl group reacted smoothly, but some olefins with an inner double bond did not react at all.Trifluoroacetone was also found to undergo a Friedel-Crafts type reaction with aromatic compounds.Keywords - trifluoroacetone; trifluoromethyl; ene reaction; homoallyl alcohol; trifluoromethylcarbinol; Lewis acid catalyzed reaction; aluminum chloride; allyl; olefin; diethyl aluminum chloride