1078711-01-9Relevant academic research and scientific papers
Diversity in gold- and silver-catalyzed cycloisomerization of epoxide-alkyne functionalities
Lin, Guan-You,Li, Chia-Wen,Hung, Siao-Hua,Liu, Rai-Shung
scheme or table, p. 5059 - 5062 (2009/05/31)
(Chemical Equation Presented) We report Au(I)- and Ag(I)-catalyzed cycloisomerizations of epoxide-alkyne functionalities in both aromatic and nonaromatic systems, leading to diversified carbocyclic and heterocyclic frameworks with high chemoselectivities. The use of such cycloisomerizations is reflected by a facile access to the cores of natural pallidol and gibberic acid.
