1078710-90-3Relevant academic research and scientific papers
Gold-catalyzed oxidative cyclizations of 2-oxiranyl-1-alkynylbenzenes for diastereoselective synthesis of highly substituted 2-hydroxyindanones
Chaudhuri, Rupsha,Liu, Rai-Shung
, p. 2589 - 2592 (2011/12/01)
We report the gold-catalyzed oxidative cyclizations of 2-oxiranyl-1- alkynylbenzenes into highly substituted 2-hydroxyindanone frameworks bearing a tertiary alcohol. Such gold-catalyzed reactions comprise an initial internal redox reaction, sulfoxide oxidation of α-carbonyl gold-carbenoids, followed by gold-catalyzed formal ene reactions on the resulting diketone intermediates. Copyright
