1079049-45-8

Basic information

• Product Name: 1-(hex-5-en-1-yn-3-yl)-4-methoxybenzene
• Synonyms: 1-(hex-5-en-1-yn-3-yl)-4-methoxybenzene
• CAS NO: 1079049-45-8
• Molecular Weight: 186.254
• Mol File: 1079049-45-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-(hex-5-en-1-yn-3-yl)-4-methoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(hex-5-en-1-yn-3-yl)-4-methoxybenzene(1079049-45-8)
• EPA Substance Registry System: 1-(hex-5-en-1-yn-3-yl)-4-methoxybenzene(1079049-45-8)

Safety Data

• Hazardous Substances Data: 1079049-45-8(Hazardous Substances Data)

Upstream product

• 19115-30-1 1-(4-methoxyphenyl)-2-propyn-1-ol 
• 762-72-1 allyl-trimethyl-silane 
• 123-11-5 4-methoxy-benzaldehyde 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 99520-55-5 3-acetoxy-3-(4-methoxyphenyl)prop-1-yne 
• 106-95-6 allyl bromide 

Relevant articles and documents

Well-Defined Chiral Gold(III) Complex Catalyzed Direct Enantioconvergent Kinetic Resolution of 1,5-Enynes

The development of a gold(III) catalyzed direct enantioconvergent 1,5-enyne cycloisomerization and kinetic resolution reaction is described. The transformation results in highly enantioenriched bicyclo[3.1.0]hexenes at all levels of conversion, with no racemization or symmetrization taking place during the course of the reaction, and simultaneously affords optically enriched 1,5-enynes. This report marks the first highly enantioselective transformation catalyzed by a well-defined cationic gold(III) catalyst and demonstrates the unique potential of gold(III) complexes in enantioselective catalysis.

HBF4-Catalysed Nucleophilic Substitutions of Propargylic Alcohols

The activity of HBF4 (aqueous solution) as a catalyst in propargylation reactions is presented. Diverse types of nucleophiles were employed in order to form new C-O, C-N and C-C bonds in technical acetone and in air. Good to excellent yields and good chemoselectivities were obtained using low acid loading (typically 1 mol-%) under simple reaction conditions. The activity of HBF4 (aq. solution) as a catalyst in propargylation reactions is presented. C-O, C-N and C-C bonds were formed in technical acetone and in air. Good to excellent yields were obtained using low acid loading (typically 1 mol-%) under mild reaction conditions.

Zinc-mediated allylation of aryl 2-propynyl acetates: A facile synthesis of 1,5-enynes

Aryl 2-propynyl acetates undergo smooth allylation with allylzinc bromide (generated in situ from allyl bromide and zinc metal) in THF at room temperature under mild conditions to furnish the corresponding 1,5-enynes in good to excellent yields and with high selectivity. Indium metal is also found to accomplish the nucleophilic substitution of aryl 2-propynylic acetates with allyl bromide. Copyright