1079398-13-2Relevant academic research and scientific papers
Synthesis of gem-difluoroalkenes via β-fluoride elimination of organorhodium(I)
Miura, Tomoya,Ito, Yoshiteru,Murakami, Masahiro
supporting information; experimental part, p. 1006 - 1007 (2009/04/06)
Treatment of α-(trifluoromethyl)styrenes with arylboronic esters and MeMgCl in the presence of a rhodium(I) catalyst affords gem-difluoroalkenes. The reaction proceeds through the addition of arylrhodium(I) species across the electron-deficient carbon-carbon double bond and the subsequent β-fluoride elimination. Copyright
