1079988-46-7

Basic information

• Product Name: dodecyl 2-methylphenyl sulfide
• Synonyms: dodecyl 2-methylphenyl sulfide
• CAS NO: 1079988-46-7
• Molecular Weight: 292.529
• Mol File: 1079988-46-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: dodecyl 2-methylphenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: dodecyl 2-methylphenyl sulfide(1079988-46-7)
• EPA Substance Registry System: dodecyl 2-methylphenyl sulfide(1079988-46-7)

Safety Data

• Hazardous Substances Data: 1079988-46-7(Hazardous Substances Data)

Upstream product

• 932-31-0 ortho-tolylmagnesium bromide 
• 2757-37-1 didodecyl disulfide 
• 615-37-2 ortho-methylphenyl iodide 
• 112-55-0 1-dodecylthiol 
• 529-19-1 2-Methylbenzonitrile 

Downstream Products

• 1595-11-5 2-butyltoluene 
• 4501-35-3 1-cyclohexyl-2-methylbenzene 

Relevant articles and documents

Nickel-Catalyzed Thiolation of Aryl Nitriles

A nickel-catalyzed thiolation of aryl nitriles has been developed to access functionalized aryl thioethers. The ligand dcype (1,2-bis(dicyclohexylphosphino)ethane) as well as the base KOtBu (potassium tert-butoxide) are essential to achieve this transformation. This scalable and practical process involves both a C?C bond activation and a C?S bond formation. Furthermore, this reaction shows a high functional-group tolerance and enables the late-stage functionalization of important molecules.

Efficient recyclable CuI-nanoparticle-catalyzed S-arylation of thiols with aryl halides on water under mild conditions

CuI nanoparticles efficiently catalyzed the C-S cross coupling of aryl and alkyl thiols with aryl halides in the absence of ligands on water under mild conditions. A wide range of diaryl sulfides and aryl alkyl sulfides are synthesized in good to excellent yields utilizing this protocol. This procedure is particularly noteworthy given its mild conditions, avoiding the undesired formation of disulfides through oxidation of thiols. The recovery and successful reutilization of the catalyst is described. Furthermore, the directed synthesis of bisarylated product is presented. The Royal Society of Chemistry 2012.