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1595-11-5

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1595-11-5 Usage

Uses

Different sources of media describe the Uses of 1595-11-5 differently. You can refer to the following data:
1. O-BUTYLTOLUENE is a component of fuel oils. It can be used for the preparation of biofuel and flammable gas.
2. 2-Butyltoluene, is a component of fuel oils. It can be used for the preparation of biofuel and flammable gas.

Check Digit Verification of cas no

The CAS Registry Mumber 1595-11-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,5,9 and 5 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1595-11:
(6*1)+(5*5)+(4*9)+(3*5)+(2*1)+(1*1)=85
85 % 10 = 5
So 1595-11-5 is a valid CAS Registry Number.
InChI:InChI=1/C11H16/c1-3-4-8-11-9-6-5-7-10(11)2/h5-7,9H,3-4,8H2,1-2H3

1595-11-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-Butyl-2-methylbenzene

1.2 Other means of identification

Product number -
Other names 2-butyl-thiophene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1595-11-5 SDS

1595-11-5Downstream Products

1595-11-5Relevant articles and documents

Photoredox-Assisted Reductive Cross-Coupling: Mechanistic Insight into Catalytic Aryl-Alkyl Cross-Couplings

Paul, Avishek,Smith, Mark D.,Vannucci, Aaron K.

, p. 1996 - 2003 (2017/02/26)

Here, we describe a photoredox-assisted catalytic system for the direct reductive coupling of two carbon electrophiles. Recent advances have shown that nickel catalysts are active toward the coupling of sp3-carbon electrophiles and that well-controlled, light-driven coupling systems are possible. Our system, composed of a nickel catalyst, an iridium photosensitizer, and an amine electron donor, is capable of coupling halocarbons with high yields. Spectroscopic studies support a mechanism where under visible light irradiation the Ir photosensitizer in conjunction with triethanolamine are capable of reducing a nickel catalyst and activating the catalyst toward cross-coupling of carbon electrophiles. The synthetic methodology developed here operates at low 1 mol % catalyst and photosensitizer loadings. The catalytic system also operates without reaction additives such as inorganic salts or bases. A general and effective sp2-sp3 cross-coupling scheme has been achieved that exhibits tolerance to a wide array of functional groups.

Cross-coupling reactions through the intramolecular activation of Alkyl(triorgano)silanes

Nakao, Yoshiaki,Takeda, Masahide,Matsumoto, Takuya,Hiyama, Tamejiro

supporting information; scheme or table, p. 4447 - 4450 (2010/08/19)

(Figure Presented) Cross-Si-ing the Jordan: Cross-coupling reactions of 2-(2-hydroxyprop-2-yl)phenylsubstituted alkylsilanes with a variety of aryl halides proceed in the presence of palladium and copper catalysts. The use of K3PO4 base allows for highly chemoselective alkyl coupling with both primary and secondary alkyl groups (Alk).

Ligand exchange as the first irreversible step in the nickel-catalyzed cross-coupling reaction of grignard reagents

Yoshikai, Naohiko,Matsuda, Hirokazu,Nakamura, Eiichi

supporting information; experimental part, p. 15258 - 15259 (2009/03/12)

Mechanistic studies of the Ni-catalyzed cross-coupling reaction of Grignard reagents through analysis of kinetic isotope effects and theoretical calculations indicated that the product-to-substrate ligand exchange process is the first irreversible step and affects the turnover efficiency and selectivity of the reaction. On the other hand, the oxidative addition step is the first irreversible step in Pd catalysis. This finding has useful implications for the development of efficient Ni catalysis and also illustrates the importance of the catalyst turnover step that has so far received less attention than subsequent catalytic steps. Copyright

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