108025-29-2Relevant academic research and scientific papers
Retro-ene type fragmentation of allylic dithiolcarbonates
Eto, Masashi,Nishimoto, Mitsuhiro,Kubota, Shoji,Matsuoka, Toshikazu,Harano, Kazunobu
, p. 2445 - 2448 (1996)
The formation of 2-alkenyl alkyl sulfides from S-(2-alkenyl) S-alkyl dithiocarbonates with extrusion of COS was found to be effectively catalyzed by Lewis acids. The ab initio calculations strongly suggested that the reaction falls into category of 'retro-alkylthio-ene' reaction.
Palladium-catalyzed insertion reactions of trimethylsilyldiazomethane
Greenman, Kevin L,Carter, David S,Van Vranken, David L
, p. 5219 - 5225 (2007/10/03)
Palladium(II) salts catalyze the Kirmse reaction of allylsulfides with trimethylsilyldiazomethane (TMSD) to give homoallylsulfides. Similarly, TMSD can intercept ArPdX intermediates generated during Stille couplings to give benzhydryl derivatives. The yie
Phenyl derivatives
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, (2008/06/13)
Phenyloxy, phenylsulfinyl, phenylthio, phenylsulfonyl, benzyloxy, benzylthio, benzylsulfinyl, or benzylsulfonyl, alkyl or alkenyl derivatives wherein the alkyl or alkenyl group contains at least 7 carbon atoms which are useful in killing and preventing proliferation of insects by upsetting their hormone balance.
