Tetrahedron Letters p. 2445 - 2448 (1996)
Update date:2022-09-26
Topics: NMR spectroscopy Mass spectrometry Purification Reaction Conditions Fragmentation Allylic
Eto, Masashi
Nishimoto, Mitsuhiro
Kubota, Shoji
Matsuoka, Toshikazu
Harano, Kazunobu
The formation of 2-alkenyl alkyl sulfides from S-(2-alkenyl) S-alkyl dithiocarbonates with extrusion of COS was found to be effectively catalyzed by Lewis acids. The ab initio calculations strongly suggested that the reaction falls into category of 'retro-alkylthio-ene' reaction.
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