108142-59-2Relevant academic research and scientific papers
The effect of the phosphoryl group on the rate and mechanism of SN-substitution at the saturated carbon atoms
Tsvetkov, E. N.,Tkachenko, S. E.,Yarkevich, A. N.
, p. 339 - 341 (2007/10/02)
The reactivity of diarylphosphine oxides RR'P(O)CH2X with p-O2NC6H4ONa in DMF have been studied.The reaction rate increases with the electrodrawing properties of the substituents on R and R' in the following way: p-Me2NC6H4 2 reaction rate of diphenylphosphine oxides has been investigated.The reactivity increases as follows Cl I Br OTs.A reaction mechanism is suggested.
