108147-35-9

Upstream product

• 95763-67-0 rel-(2R,3S)-1,2-epoxy-2-methyl-6-(trimethylsilyl)-5-hexyn-3-ol 
• 95763-62-5 (2E,6E)-3,7-dimethyl-8-<(2-tetrahydropyranyl)oxy>-2,6-octadienyl phenyl sulfone 
• 95763-61-4 3,7-dimethyl-1-(phenylsulfonyl)-8-hydroxy-2(E),6(E)-octadiene 
• 95763-65-8 3-(1-Ethoxy-ethoxy)-2-methyl-hex-1-en-5-yne 
• 95763-66-9 2-methyl-6-(trimethylsilyl)-1-hexen-5-yn-3-ol 
• 56691-80-6 geranyl phenyl sulfone 

Downstream Products

• 108104-33-2 rel-(3R,5S,6R)-(9E,13E)-3-<(phenylsulfonyl)carbomethoxymethyl>-5,6-dihydroxy-15-(pivalyloxy)-6,10,14-trimethylpentadeca-9,13-dienoic acid δ-lactone 
• 108104-34-3 methyl rel-(1R,2S,12R,13S)-(5E,9E)-12-(phenylsulfonyl)-2-hydroxy-2,6,10-trimethyl-15-oxo-16-oxabicyclo<11.3.1>heptadeca-5,9-diene-12-carboxylate 

Relevant academic research and scientific papers

Coupling of Allylic Alcohol Epoxides with Sulfur-Stabilized Allylic Anions

A study of the coupling of epoxy alcohol 15 with sulfur-stabilized allylic anions was undertaken as a route to dienes 16 and 17.The allylic sulfone 9a upon deprotonation with n-butyllithium in THF-HMPA undergoes smooth coupling with the epoxy magnesio alk