Coupling of Allylic Alcohol Epoxides with Sulfur-Stabilized Allylic Anions

DOI: 10.1021/jo00210a009

Source and publish data:

Journal of Organic Chemistry p. 1602 - 1606 (1985)

Update date:2022-08-03

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Authors:

Marshall, James A.

Andrews, Robert C.

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Article abstract of DOI:10.1021/jo00210a009

A study of the coupling of epoxy alcohol 15 with sulfur-stabilized allylic anions was undertaken as a route to dienes 16 and 17.The allylic sulfone 9a upon deprotonation with n-butyllithium in THF-HMPA undergoes smooth coupling with the epoxy magnesio alk

Full text of DOI:10.1021/jo00210a009

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