Coupling of Allylic Alcohol Epoxides with Sulfur-Stabilized Allylic Anions

DOI: 10.1021/jo00210a009

Source and publish data:

Journal of Organic Chemistry p. 1602 - 1606 (1985)

Update date:2022-08-03

Topics:

Authors:

Marshall, James A.

Andrews, Robert C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00210a009

A study of the coupling of epoxy alcohol 15 with sulfur-stabilized allylic anions was undertaken as a route to dienes 16 and 17.The allylic sulfone 9a upon deprotonation with n-butyllithium in THF-HMPA undergoes smooth coupling with the epoxy magnesio alk

Full text of DOI:10.1021/jo00210a009

Products guided by the article

Product name:rel-(4S,5R)-(8E,12E)-5,9,13-trimethyl-7-(phenylsulfonyl)-14-<(2-tetrahydropyranyl)oxy>-8,12-tetradecadien-1-yne-4,5-diol

Cas No:108147-35-9

R&D Labs maybe for 108147-35-9

BAODING SINO-CHEM INDUSTRY CO.,LTD

Contact:0312-5956088

Address:NO.8 FUXING ROAD,CHINA
Ceresking Ecology & Technology co.,ltd

Contact:86 22 66218397

Address:Room 1613, Zheshang Mansion, No. 1988, Yingbin Avenue, Binhai New District, Tianjin,China.
Weifang Yuexiang Chemical Co.,Ltd

Contact:86-536-8734188

Address:Economic development zone Weifang city ,Shandong province ,China
QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

website:http://www.obn.com.cn

Contact:+86-15005320811 +86-532-80681989

Address:F35 Parkson Mansion No.44-60 Zhongshan Rd.
Tianjin Anda North Industrial & Business Co.Ltd.

Contact:86-22-24999306

Address:No.11 Erwei Road,Dongli Development Area,Tianjin,China

Relevant to this article

Unexpected hydrolytic instability of N-acylated amino acid amides and peptides

Doi:10.1021/jo500273f
(2014)
Out-Basicity of 1,8-bis(dimethylamino)naphthalene: The experimental and theoretical challenge

Doi:10.1039/c3ob41986j
(2014)
Synthesis, Properties, and X-ray Structure of 6-Aza-5,7,12,14-tetrathiapentacene as a Novel Polyheterocyclic Electron Donor, and Related Compounds

Doi:10.1021/jo00100a022
(1994)
Chemoenzymatic Synthesis of Optically Pure 1,3,4-Oxadiazol-2(3H)-ones with Acaricidal Activity

Doi:10.1021/jf00047a042
(1994)
Synthesis and comparative study of homoisofagomines and analogues as glycosidase inhibitors

Doi:10.1002/ejoc.201301279
(2014)
Application of alkoxyamine in self-healing of epoxy

Doi:10.1039/c4ta00130c
(2014)

Article Doi