108182-13-4Relevant academic research and scientific papers
Orthoamides by selective borohydride reduction of N,N′,N″-triacyl- and N,N′,N″-tri(alkoxycarbonyl)-guanidines
Davis, Matthew C.,Groshens, Thomas J.
, p. 427 - 431 (2019)
N,N′,N″-Triacylguanidines and N,N′,N″-tri(alkoxycarbonyl)guanidines were prepared and reduced with borohydride salts in a mixture of tetrahydrofuran and acetic acid to give triacyl and tri(alkoxycarbonyl) orthoamides in yields of 40–85%. However, similar
Carbonyl Diisocyanate: A New Preparation and Some Reactions
Akteries, Bernhard,Jochims, Johannes C.
, p. 83 - 95 (2007/10/02)
A preparation of carbonyl diisocyanate (2) from tri-n-butyltin isocyanate (4) and phosgene is reported.Correspondingly, the acyl isocyanates 6 were obtained from 4 with acyl chlorides.On standing, carbonyl diisocyanate trimerizes reversibly to the triazine 9, which could also be prepared by independent syntheses from the triazines 3 or 12.Reported are reactions of carbonyl diisocyanate with water, hydrogen sulfide, alcohols, phenol, phenol + carbodiimides, thiols, amines, primary ammonium salts, and N-unsubstituted imines leading to compounds 14-24.
