108202-81-9Relevant academic research and scientific papers
Acylphosphonates. 6.1 Reaction Mechanism of Zn/Me3SiCl Mediated Conversion of 2,2,2-Trichloroethoxycarbonylphosphonates to Silyl Phosphites.
Fujii, Mitsuo,Ozaki, Kouji,Kume, Akiko,Sekine, Mitsuo,Hata, Tsujiaki
, p. 3365 - 3368 (1986)
It was elucidated by 31P nmr spectroscopy that the conversion of 2,2,2-trichloroethoxycarbonylphosphonates to dialkyl trimethylsilyl phosphites by treatment with Me3SiCl-Zn-acetylacetone proceed with retention configuration at phosphorus.In this study, optical active dinucleoside 2,2,2-trichloroethoxycarbonylphosphonates were synthesized and employed as the reaction substrates.
