
Tetrahedron Letters p. 3365 - 3368 (1986)
Update date:2022-09-26
Topics:
Fujii, Mitsuo
Ozaki, Kouji
Kume, Akiko
Sekine, Mitsuo
Hata, Tsujiaki
It was elucidated by 31P nmr spectroscopy that the conversion of 2,2,2-trichloroethoxycarbonylphosphonates to dialkyl trimethylsilyl phosphites by treatment with Me3SiCl-Zn-acetylacetone proceed with retention configuration at phosphorus.In this study, optical active dinucleoside 2,2,2-trichloroethoxycarbonylphosphonates were synthesized and employed as the reaction substrates.
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Doi:10.1016/j.bmc.2008.09.001
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(2008)